Bis(μ2-N-methyl-N-phenyldithiocarbamato)-κ3 S,S′:S;κ3 S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ2 S,S′)cadmium]: crystal structure and Hirshfeld surface analysis
نویسندگان
چکیده
The title compound, [Cd2(C8H8NS2)4], is a centrosymmetric dimer with both chelating and μ2-tridentate di-thio-carbamate ligands. The resulting S5 donor set defines a CdII coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C-H⋯S and C-H⋯π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π-π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.
منابع مشابه
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عنوان ژورنال:
دوره 73 شماره
صفحات -
تاریخ انتشار 2017